1009-93-4
- Product Name：2,2,4,4,6,6-Hexamethylcyclotrisilazane(D3N)
- Molecular Formula：C6H21N3Si3
- Purity：99%
- Molecular Weight：219.509
Product Details
Manufacturers supply cost-effective and customizable 2,2,4,4,6,6-Hexamethylcyclotrisilazane(D3N) 1009-93-4
- Molecular Formula:C6H21N3Si3
- Molecular Weight:219.509
- Appearance/Colour:clear colorless liquid
- Vapor Pressure:1.591mmHg at 25°C
- Melting Point:-10 °C(lit.)
- Refractive Index:n20/D 1.445(lit.)
- Boiling Point:188 °C at 760 mmHg
- PKA:14.76±0.20(Predicted)
- Flash Point:63.5 °C
- PSA：36.09000
- Density:0.91 g/cm3
- LogP:1.86060
2,2,4,4,6,6-Hexamethylcyclotrisilazane(Cas 1009-93-4) Usage
|
Hazard |
Moderately toxic by ingestion. |
|
Flammability and Explosibility |
Flammable |
|
Purification Methods |
Purify it by fractional distillation at atmospheric pressure until the temperature reaches 200o. It is moisture sensitive. The residue in the flask is mostly octamethylcyclotetrasilazane. [Brewer & Haber J Am Chem Soc 70 3888 1948, Beilstein 4 III 1887.] |
InChI:InChI=1/C6H21N3Si3/c1-8-10-7-11(3,4)9(2)12(8,5)6/h7H,10H2,1-6H3
1009-93-4 Relevant articles
-
Osthoff,Kantor
, p. 55,56, 57 (1957)
-
-
Fink
, p. 1159 (1968)
-
-
Wannagat et al.
, p. 168,169,171,173 (1971)
-
-
Wannagat,U.,Schreiner,G.
, p. 1376 - 1382 (1968)
-
-
Wannagat et al.
, p. 1825,1827-1832 (1971)
-
-
Jarvie,Lewis
, p. 1073,1074 (1963)
-
-
Andrianov et al.
, p. 129,136 (1965)
-
Method for preparing hexamethyl cyclotrisiloxane
-
Paragraph 0017-0032, (2018/03/24)
The invention discloses a method for pre...
SYNTHESIS OF SPIRO- AND CARBOCYCLOSILAZAOXANES AND THEIR 1H and 29Si NMR SPECTRA
Zachernyuk, A. B.,Isaev, V. B.,Lavrukhin, B. D.,Zhdanov, A. A.
, p. 1879 - 1887 (2007/10/02)
-
COAMMONOLYSIS OF 1,2-BIS(CHLORODIMETHYLSILYL)-2,2,4,4-TETRAMETHYLCYCLODISILAZANE WITH DICHLORODIMETHYLSILANE
Morgunova, M. M.,Varezhkin, Yu. M.,Chernyshev, A. E.,Bochkarev, V. N.,Zhinkin, D. Ya.
, p. 1633 - 1635 (2007/10/02)
-
Organosilicon esters derivated from triethanolamine. Synthesis and pharmacological properties
Pometan,Dumas,Fourtillan,et al.
, p. 425 - 429 (2007/10/02)
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1009-93-4 Process route
-
-
1020-84-4
2,2,4,4,6,6,8,8-octamethyl-cyclotetrasilazane
-
-
1009-93-4
2,2,4,4,6,6-hexamethylcyclotrisilazane
| Conditions | Yield |
|---|---|
|
With
dimethylsilicon dichloride;
In
dichloromethane;
at -20 - 0 ℃;
for 2h;
Solvent;
Temperature;
|
92% |
-
-
75-78-5,30107-43-8
dimethylsilicon dichloride
-
-
1009-93-4
2,2,4,4,6,6-hexamethylcyclotrisilazane
-
-
1020-84-4
2,2,4,4,6,6,8,8-octamethyl-cyclotetrasilazane
| Conditions | Yield |
|---|---|
|
With
ammonia; benzene;
|
|
|
With
ammoniac;
In
benzene;
at 0 ℃;
|
|
|
With
NH3;
In
ammonia;
NH3 (liquid); introduction of (CH3)2SiCl2 into liq. NH3;; evapn. of NH3; extraction with benzene; recrystn. from petrolether;;
|
|
|
With
NH3;
In
benzene;
introduction of a stream of NH3 into (CH3)2SiCl2 in benzene;; recrystn. from petrolether;;
|
|
|
With
ammonia; benzene;
|
1009-93-4 Upstream products
-
75-78-5
dimethylsilicon dichloride
-
51840-40-5
2,2-dichlorotetramethylcyclotrisiloxane
-
2329-10-4
1,3-bis(chlorodimethylsilyl)-2,2,4,4-tetramethylcyclodisilazane
-
7664-41-7
ammonia
1009-93-4 Downstream products
-
17933-43-6
2,2-dimethyl-1,3-diphenyl-[1,3,5,2]triazasilinane-4,6-dione
-
18752-97-1
2,2-dimethyl-1,3,5-triphenyl-[1,3,5,2]triazasilinane-4,6-dione
-
2182-66-3
dimethyldiacetoxysilane
-
1452-13-7
1,3-bis-(4-bromo-phenyl)-2,2-dimethyl-[1,3,5,2]triazasilinane-4,6-dione
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