768-33-2
- Product Name：Chlorodimethylphenylsilane(DMPCS)
- Molecular Formula：C8H11ClSi
- Purity：99%
- Molecular Weight：170.714
Product Details
Good factory supply good Chlorodimethylphenylsilane(DMPCS) 768-33-2
- Molecular Formula:C8H11ClSi
- Molecular Weight:170.714
- Appearance/Colour:clear colorless to light yellow liquid
- Vapor Pressure:0.572mmHg at 25°C
- Melting Point:< 0 °C
- Refractive Index:n20/D 1.509(lit.)
- Boiling Point:196 °C at 760 mmHg
- Flash Point:61.7 °C
- PSA：0.00000
- Density:1 g/cm3
- LogP:2.33750
Chlorodimethylphenylsilane(Cas 768-33-2) Usage
|
Chemical Description |
Chlorodimethylphenylsilane is an organosilicon compound used as a reagent in organic synthesis. |
|
Purification Methods |
Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE. |
InChI:InChI=1/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3
768-33-2 Relevant articles
A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes
Naganawa, Yuki,Nakajima, Yumiko,Sakamoto, Kei
supporting information, p. 601 - 606 (2021/01/13)
Direct catalytic transformation of chlor...
METHOD FOR PRODUCING ARYLSILANE COMPOUND CONTAINING HALOSILANE COMPOUND AS RAW MATERIAL
-
Paragraph 0073-0077, (2020/03/06)
PROBLEM TO BE SOLVED: To provide a metho...
Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane
Fan, Xuanzi,Xiao, Pin,Jiao, Zeqing,Yang, Tingting,Dai, Xiaojuan,Xu, Wengang,Tan, Jin Da,Cui, Ganglong,Su, Hongmei,Fang, Weihai,Wu, Jie
supporting information, p. 12580 - 12584 (2019/08/16)
Chlorosilanes are versatile reagents in ...
METHOD FOR PRODUCING HALOSILANE
-
Paragraph 0028; 0029; 0030; 0031; 0032, (2019/07/31)
PROBLEM TO BE SOLVED: To provide a metho...
768-33-2 Process route
-
-
75-77-4
chloro-trimethyl-silane
-
-
1825-58-7
dimethyl(ethoxy)phenylsilane
-
-
1825-62-3
ethyl trimethylsilyl ether
-
-
768-33-2
phenyldimethylsilyl chloride
| Conditions | Yield |
|---|---|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
In
toluene;
at 20 ℃;
Equilibrium constant;
Thermodynamic data;
ΔG;
|
-
![[bis-(dimethyl-phenyl-silanyl)-methylene]-(2,6-diisopropyl-phenyl)-amine](/upload/2025/7/bb342349-a426-4514-8100-360cf6ed9001.png)
-
[bis-(dimethyl-phenyl-silanyl)-methylene]-(2,6-diisopropyl-phenyl)-amine
-
-
2008-61-9
2,6-diisopropylphenylisocyanide
-
-
768-33-2
phenyldimethylsilyl chloride
| Conditions | Yield |
|---|---|
|
With
tetrachloromethane;
In
benzene-d6;
at 20 ℃;
for 2h;
Photolysis;
|
768-33-2 Upstream products
-
676-58-4
methylmagnesium chloride
-
75-78-5
dimethylsilicon dichloride
-
1825-58-7
dimethyl(ethoxy)phenylsilane
-
75-36-5
acetyl chloride
768-33-2 Downstream products
-
75-78-5
dimethylsilicon dichloride
-
75-77-4
chloro-trimethyl-silane
-
18057-04-0
phenyldimethyl(t-butylperoxy)silane
-
14920-92-4
pentamethyl(phenyl)disiloxane
Relevant Products
-
3-ChloropropylmethyldiethoxysilaneCAS：13501-76-3
-
Chlorodiphenylmethylsilane(DPMCS)CAS：144-79-6
-
Octaphenylcyclotetrasiloxane(D4PH)CAS：546-56-5