
29681-57-0
- Product Name:Tert-butyldimethylsilane(TBDMS)
- Molecular Formula:C6H16Si
- Purity:99%
- Molecular Weight:116.279
Product Details
Cost-effective and customizable Tert-butyldimethylsilane(TBDMS) 29681-57-0 supplier
- Molecular Formula:C6H16Si
- Molecular Weight:116.279
- Melting Point:13°C
- Refractive Index:n20/D 1.4(lit.)
- Boiling Point:82.697 °C at 760 mmHg
- Flash Point:-22.778 °C
- PSA:0.00000
- Density:0.701 g/mL at 25 °C(lit.)
- LogP:2.27320
T-BUTYLDIMETHYLSILANE(Cas 29681-57-0) Usage
General Description |
T-Butyldimethylsilane, also known as tert-Butyldimethylsilane or TBDMS, is an organosilicon compound that is primarily used in the field of organic chemistry as a protecting agent. Its molecular formula is C6H16Si and its structure consists of a t-butyl group (C4H9) and two methyl groups (CH3), bonded to a silicon atom. This substance is colorless, has a mild smell, and is insoluble in water. It's used to protect reactive hydroxy, amine, or carboxy groups during chemical reactions, preventing them from unwanted participation and can be removed afterwards with ease under controlled conditions. Additionally, it plays a role in the manufacturing of certain pharmaceuticals and silicone-based products. |
InChI:InChI=1/C6H15Si/c1-6(2,3)7(4)5/h1-5H3
29681-57-0 Relevant articles
Activation of Homolytic Si-Zn and Si-Hg Bond Cleavage, Mediated by a Pt0 Complex, via Novel Pt-Zn and Pt-Hg Compounds
Kratish, Yosi,Molev, Gregory,Kostenko, Arseni,Sheberla, Dennis,Tumanskii, Boris,Botoshansky, Mark,Shimada, Shigeru,Bravo-Zhivotovskii, Dmitry,Apeloig, Yitzhak
supporting information, p. 11817 - 11821 (2015/10/05)
The thermally stable [(tBuMe2Si)2M] (M=Z...
Novel catalytic hydrogenolysis of silyl enol ethers by the use of acidic ruthenium dihydrogen complexes
Takei, Izuru,Nishibayashi, Yoshiaki,Ishii, Youichi,Mizobe, Yasushi,Uemura, Sakae,Hidai, Masanobu
, p. 32 - 42 (2007/10/03)
Treatment of 1-trimethylsilyloxy-1-cyclo...
29681-57-0 Process route
-
-
62791-22-4
tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane

-
-
29681-57-0
tert-butyldimethylsilane

-
-
2979-36-4
<2-D>Cyclohexanone
Conditions | Yield |
---|---|
With
deuterium;
[RuCl(η2-H2)(dppe)2]OTf;
In
1,2-dichloro-ethane;
at 50 ℃;
for 48h;
under 760 Torr;
|
40 % Chromat. |
-
-
1380397-69-2
Zn(Si(CH3)2(C(CH3)3))2

-
-
29681-57-0
tert-butyldimethylsilane

-
-
63262-93-1
1,2-di-tert-butyl-1,1,2,2-tetramethyldisilane
Conditions | Yield |
---|---|
With
[(1,2-bis(dimethylphosphanyl)ethane)Pt(PEt3)2];
In
hexane;
at 80 ℃;
for 2.5h;
Schlenk technique;
|
29681-57-0 Upstream products
-
tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane
-
Zn(Si(CH3)2(C(CH3)3))2
29681-57-0 Downstream products
-
1-tert-butyldimethylsilyloxy-2-phenylethane
-
(Z)-β-tert-butyldimethylsilyloxystyrene
-
(E)-β-tert-butyldimethylsilyloxystyrene
-
t-butyldimethylsiyl triflate
Relevant Products
-
Diethylenetriaminopropylmethyldimethoxysilane
CAS:35141-30-1
-
Bis(aminopropyl)tetramethyldisiloxane(BAPTMDS)
CAS:2469-55-8
-
Dimethylsilyldiethylamine(DMSDEA)
CAS:13686-66-3