4420-74-0
- Product Name:3-Mercaptopropyltrimethoxysilane
- Molecular Formula:C6H16O3SSi
- Purity:99%
- Molecular Weight:196.343
Product Details
Other Grade
Z-6062 (Dow Corning), A-189 (Momentive), KBM-803 (Shinetsu, Japan), GF70 (Wacker), KH-590 (CAS)
Typical Properties
| Order | Index | Specifications |
|---|---|---|
| 1 | Appearance | Colorless to pale yellow clear liquid |
| 2 | purity | ≥98.0% |
| 3 | Color, Pt-Co | ≤20 |
| 4 | Density 25℃ g/cm3 | 1.0450±0.0100 |
Application
Mercaptopropyl trimethoxysilane is a reactive and cross-linked silane coupling agent with sulfhydryl functional groups, which is widely used.
1. As a metal surface rust inhibitor with special effects, used to treat gold, silver, copper and other metal surface, which can improve its corrosion resistance, oxidation resistance and improve its adhesion to polymer materials.
2. It is widely used in filling polymer materials, and can be applied to thermosetting and thermoplastic polymer materials, such as epoxy, phenol sulfonate, polyvinyl chloride, polystyrene, polyinkstone, etc.
3. The effect is particularly good in the rubber industry, which can improve the mechanical properties of rubber, improve wear resistance, reduce permanent deformation, suitable for NR, EPDM, SBR, chloroether rubber, polysulfide rubber, styrene butadiene rubber, nitrile rubber, neoprene rubber and polyurethane rubber, especially suitable for light color products.
The suitable range of inorganic fillers is also very wide, can be used for glass fiber, white carbon black, quartz powder, talc, mica, fly ash clay, clay and other silicon-containing substances.
4. It can be used as a reinforcing agent and crosslinking accelerator for composite materials (such as resin-glass fiber composite materials), coatings, inks, glues and sealing materials.
5. It can be used for anti-shrink finishing of fabric in textile.
Packing and storage
Packing
This product is packaged in 200L galvanized plastic iron barrel or 1000 L IBC container ton barrel, 200 Kg/ barrel or 1000 Kg/ barrel; or other specifications to be scheduled.
Storage
This product should be stored in a cool, ventilated and dry place to prevent rain and moisture.
Reliable factory customized supply 3-Mercaptopropyltrimethoxysilane 4420-74-0
- Molecular Formula:C6H16O3SSi
- Molecular Weight:196.343
- Appearance/Colour:white to light straw liquid clear liquid
- Vapor Pressure:3.117mmHg at 25°C
- Melting Point:<-50 °C
- Refractive Index:n20/D 1.444(lit.)
- Boiling Point:198 °C at 760 mmHg
- PKA:10.47±0.10(Predicted)
- Flash Point:48.9 °C
- PSA:66.49000
- Density:0.999 g/cm3
- LogP:1.18440
Trimethoxysilylpropanethiol(Cas 4420-74-0) Usage
|
Silane coupling agent KH-590 |
Silane coupling agent KH-590 is the earliest widely applied coupling agent and so far has a history of more than 40 years. One end of its structure contains active groups such as amino group and vinyl group which are capable of having reaction with various kinds of synthetic resin molecules including epoxy, phenolic, and polyester. The other end includes either alkoxy group (e.g. methoxy, ethoxy, etc.) or a chlorine atom which are connected to silicon. These groups, in the presence of an aqueous solution or moisture in the air, can be hydrolyzed to be able to react with glass, minerals, and the surface hydroxyl group of inorganic filler to generate reactive silanols. Accordingly, the silane coupling agent is commonly used in the silicate-filled epoxy, phenolic and polyester resin systems. In addition, it can also be used for the production of the glass steel in order to improve their mechanical strength and resistance to humid environments. The organic groups of the silane coupling agent have selectivity on the reaction of the synthetic resin. In general, these organic groups don’t have enough reactivity with synthetic resin such as polyethylene, polypropylene and polystyrene, and thus having poor coupling effects. In recent years, it has been developed of new variety of silane coupling agent with better coupling effect with polyolefin. However, limited by the cost and other performance, its application is still not wide enough. Silane coupling agent is also known as silane treatment agent or primer. Its general chemical formula is Y (CH2) nSiX3 which contains organosilicon monomers with two or more different reactive groups in the molecule. It can have chemical coupling reaction with both inorganic and organic materials to increase the adhesion between the two kinds of materials. The n in the general chemical formula is an integer of 0 to 3; X is a hydrolyzable group such as chloro, methoxy, ethoxy, acetoxy, etc., It is easily to be hydrolyzed into silanols and can have reaction with inorganic materials and further bind to them; the Y is organic functional groups, such as vinyl, amino, epoxy, methacryloxy group, and mercapto group, etc., it can react with organic materials and bind to them. The performance of typical silane coupling agent is as follows: can be used for the treatment of glass fiber and inorganic filler surface; can be used as sealants, adhesives and coatings thickener; also can be applied to ensure the immobilize enzyme be attached to the glass substrate surface, sand prevention for oil well drilling, making masonry surfaces be water-repellent, endowing the coating of fluorescent lamp with a high surface resistance, and also improving the hygroscopic effect of the surface of the organic glass in the liquid chromatography. It is prepared from the adduct reaction between silicon chloroform and active group containing olefin in the catalysis of platinum and further alcoholysis. The above information is edited by the lookchem of Dai Xiongfeng. |
|
General Description |
(3-mercaptopropyl)trimethoxysilane (MPTMS) is an organosilane with a thiol group, which can be used as a self-assembled monolayer (SAM). It can be used as a conjunction reagent to immobilize a variety of nanoparticles. |
|
Flammability and Explosibility |
Notclassified |
InChI:InChI=1/C6H16O3SSi/c1-5-6(10)11(7-2,8-3)9-4/h6,10H,5H2,1-4H3
4420-74-0 Relevant articles
Synthesis method of 3-mercaptopropyltrialkoxysilane
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Paragraph 0023-0057, (2020/12/14)
The invention provides a synthesis metho...
Method for preparing mercaptosilane in virtue of thiourea process
-
, (2020/09/30)
The invention relates to a method for pr...
Synthesis method of 3- mercaptopropyltrialkoxysilane (by machine translation)
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Paragraph 0026; 0032-0036; 0041-0043, (2020/02/14)
The, invention belongs, to the technical...
Method for preparing mercaptosilane coupling agent by using phase transfer catalyst
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Paragraph 0025-0027, (2019/12/02)
The invention discloses a method for pre...
4420-74-0 Process route
-

- 2530-87-2
3-Chloropropyltrimethoxysilan

-

- 4420-74-0
3-(trimethoxysilyl)-1-propanethiol
| Conditions | Yield |
|---|---|
|
With sodium sulfide; tetrabutyl-ammonium chloride; water; In toluene; at 88 - 92 ℃; for 4h;
|
93.5% |
|
With N-octylpyridinium tetrafluoroborate; sodium hydrogen sulfide; triphenylethylphosphonium bromide; In water; at 48 - 120 ℃; for 3.5h; Reagent/catalyst; Inert atmosphere;
|
93.32% |
|
With hydrogen sulfide; sodium; In methanol;
|
|
|
With hydrogen sulfide; ammonia; In methanol;
|
|
|
Multi-step reaction with 2 steps
1: dodecyltrimethylphosphonium bromide / methanol / 130 - 140 °C
2: ethylenediamine; sodium methylate / 80 - 90 °C
With sodium methylate; dodecyltrimethylphosphonium bromide; ethylenediamine; In methanol;
|
-

- 870-23-5
prop-2-ene-1-thiol

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- 2487-90-3
trimethoxysilane

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- 4420-74-0
3-(trimethoxysilyl)-1-propanethiol
| Conditions | Yield |
|---|---|
|
prop-2-ene-1-thiol; at 62 - 64 ℃; for 0.5h; Inert atmosphere;
trimethoxysilane; In methanol; at 72 - 75 ℃; for 2h; Solvent; Temperature;
|
88.2% |
4420-74-0 Upstream products
-
64456-54-8

S-[3-(trimethoxysilyl)propyl] ethanethioate
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2530-87-2

3-Chloropropyltrimethoxysilan
-
2551-83-9

allyltrimethoxysilane
-
51826-90-5

1-bromo-3-trimethoxysilylpropane
4420-74-0 Downstream products
-
14814-09-6

3-Mercaptopropyltriethoxysilane
-
4114-28-7

diethyl hydrazodicarboxylate
-
132928-72-4

3-phenyldithiopropyltrimethoxysilane
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132928-71-3

n-Butyl(3-trimethoxysilylpropyl)disulfide
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Diethylenetriaminopropylmethyldimethoxysilane
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-
3-Mercaptopropyltriethoxysilane
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-
3-Mercaptopropylmethyldimethoxysilane
CAS:31001-77-1
