4420-74-0

  • Product Name:3-Mercaptopropyltrimethoxysilane
  • Molecular Formula:C6H16O3SSi
  • Purity:99%
  • Molecular Weight:196.343
Inquiry

Product Details

Reliable factory customized supply 3-Mercaptopropyltrimethoxysilane 4420-74-0

  • Molecular Formula:C6H16O3SSi
  • Molecular Weight:196.343
  • Appearance/Colour:white to light straw liquid clear liquid 
  • Vapor Pressure:3.117mmHg at 25°C 
  • Melting Point:<-50 °C 
  • Refractive Index:n20/D 1.444(lit.)  
  • Boiling Point:198 °C at 760 mmHg 
  • PKA:10.47±0.10(Predicted) 
  • Flash Point:48.9 °C 
  • PSA:66.49000 
  • Density:0.999 g/cm3 
  • LogP:1.18440 

Trimethoxysilylpropanethiol(Cas 4420-74-0) Usage

Silane coupling agent KH-590

Silane coupling agent KH-590 is the earliest widely applied coupling agent and so far has a history of more than 40 years. One end of its structure contains active groups such as amino group and vinyl group which are capable of having reaction with various kinds of synthetic resin molecules including epoxy, phenolic, and polyester. The other end includes either alkoxy group (e.g. methoxy, ethoxy, etc.) or a chlorine atom which are connected to silicon. These groups, in the presence of an aqueous solution or moisture in the air, can be hydrolyzed to be able to react with glass, minerals, and the surface hydroxyl group of inorganic filler to generate reactive silanols. Accordingly, the silane coupling agent is commonly used in the silicate-filled epoxy, phenolic and polyester resin systems. In addition, it can also be used for the production of the glass steel in order to improve their mechanical strength and resistance to humid environments. The organic groups of the silane coupling agent have selectivity on the reaction of the synthetic resin. In general, these organic groups don’t have enough reactivity with synthetic resin such as polyethylene, polypropylene and polystyrene, and thus having poor coupling effects. In recent years, it has been developed of new variety of silane coupling agent with better coupling effect with polyolefin. However, limited by the cost and other performance, its application is still not wide enough. Silane coupling agent is also known as silane treatment agent or primer. Its general chemical formula is Y (CH2) nSiX3 which contains organosilicon monomers with two or more different reactive groups in the molecule. It can have chemical coupling reaction with both inorganic and organic materials to increase the adhesion between the two kinds of materials. The n in the general chemical formula is an integer of 0 to 3; X is a hydrolyzable group such as chloro, methoxy, ethoxy, acetoxy, etc., It is easily to be hydrolyzed into silanols and can have reaction with inorganic materials and further bind to them; the Y is organic functional groups, such as vinyl, amino, epoxy, methacryloxy group, and mercapto group, etc., it can react with organic materials and bind to them. The performance of typical silane coupling agent is as follows: can be used for the treatment of glass fiber and inorganic filler surface; can be used as sealants, adhesives and coatings thickener; also can be applied to ensure the immobilize enzyme be attached to the glass substrate surface, sand prevention for oil well drilling, making masonry surfaces be water-repellent, endowing the coating of fluorescent lamp with a high surface resistance, and also improving the hygroscopic effect of the surface of the organic glass in the liquid chromatography. It is prepared from the adduct reaction between silicon chloroform and active group containing olefin in the catalysis of platinum and further alcoholysis. The above information is edited by the lookchem of Dai Xiongfeng.

General Description

(3-mercaptopropyl)trimethoxysilane (MPTMS) is an organosilane with a thiol group, which can be used as a self-assembled monolayer (SAM). It can be used as a conjunction reagent to immobilize a variety of nanoparticles.

Flammability and Explosibility

Notclassified

InChI:InChI=1/C6H16O3SSi/c1-5-6(10)11(7-2,8-3)9-4/h6,10H,5H2,1-4H3

4420-74-0 Relevant articles

Synthesis method of 3-mercaptopropyltrialkoxysilane

-

Paragraph 0023-0057, (2020/12/14)

The invention provides a synthesis metho...

Method for preparing mercaptosilane in virtue of thiourea process

-

, (2020/09/30)

The invention relates to a method for pr...

Synthesis method of 3- mercaptopropyltrialkoxysilane (by machine translation)

-

Paragraph 0026; 0032-0036; 0041-0043, (2020/02/14)

The, invention belongs, to the technical...

Method for preparing mercaptosilane coupling agent by using phase transfer catalyst

-

Paragraph 0025-0027, (2019/12/02)

The invention discloses a method for pre...

4420-74-0 Process route

3-Chloropropyltrimethoxysilan
2530-87-2

3-Chloropropyltrimethoxysilan

3-(trimethoxysilyl)-1-propanethiol
4420-74-0

3-(trimethoxysilyl)-1-propanethiol

Conditions
Conditions Yield
With sodium sulfide; tetrabutyl-ammonium chloride; water; In toluene; at 88 - 92 ℃; for 4h;
93.5%
With N-octylpyridinium tetrafluoroborate; sodium hydrogen sulfide; triphenylethylphosphonium bromide; In water; at 48 - 120 ℃; for 3.5h; Reagent/catalyst; Inert atmosphere;
93.32%
With hydrogen sulfide; sodium; In methanol;
 
With hydrogen sulfide; ammonia; In methanol;
 
Multi-step reaction with 2 steps
1: dodecyltrimethylphosphonium bromide / methanol / 130 - 140 °C
2: ethylenediamine; sodium methylate / 80 - 90 °C
With sodium methylate; dodecyltrimethylphosphonium bromide; ethylenediamine; In methanol;
 
prop-2-ene-1-thiol
870-23-5

prop-2-ene-1-thiol

trimethoxysilane
2487-90-3

trimethoxysilane

3-(trimethoxysilyl)-1-propanethiol
4420-74-0

3-(trimethoxysilyl)-1-propanethiol

Conditions
Conditions Yield
prop-2-ene-1-thiol; at 62 - 64 ℃; for 0.5h; Inert atmosphere;
trimethoxysilane; In methanol; at 72 - 75 ℃; for 2h; Solvent; Temperature;
88.2%

4420-74-0 Upstream products

  • 64456-54-8
    64456-54-8

    S-[3-(trimethoxysilyl)propyl] ethanethioate

  • 2530-87-2
    2530-87-2

    3-Chloropropyltrimethoxysilan

  • 2551-83-9
    2551-83-9

    allyltrimethoxysilane

  • 51826-90-5
    51826-90-5

    1-bromo-3-trimethoxysilylpropane

4420-74-0 Downstream products

  • 14814-09-6
    14814-09-6

    3-Mercaptopropyltriethoxysilane

  • 4114-28-7
    4114-28-7

    diethyl hydrazodicarboxylate

  • 132928-72-4
    132928-72-4

    3-phenyldithiopropyltrimethoxysilane

  • 132928-71-3
    132928-71-3

    n-Butyl(3-trimethoxysilylpropyl)disulfide